Effect of Double-Sided, 3D-Patterned Cathode Catalyst Layers on Polymer Electrolyte Fuel Cell Performance
نویسندگان
چکیده
Optimization of the structure cathode catalyst layers (CCLs) for promoting transfer reactants and products in polymer electrolyte fuel cells (PEFCs) is important improving cell performance. In this study, using theoretical equations, we confirmed that shortened proton conduction path ionomer layer (IL) with a 3D-patterned structure, compared to IL flat-patterned can improve We experimentally investigated effect included CCLs on Based combination flat- or 3D-pattern (CL), samples were categorized as Str. 1 (3D-patterned CL without IL), 2 (flat-patterned CL), 3 4 CL). All had different morphologies. According I–V curves impedance spectra data acquired at 80 °C 40% relative humidity, showed superior performance those other CCLs. These results indicate enhanced conductivity low humidity which usually poor, thereby resulting improved
منابع مشابه
Direct Numerical Simulation Modeling of Bilayer Cathode Catalyst Layers in Polymer Electrolyte Fuel Cells
A pore-scale description of species and charge transport through a bilayer cathode catalyst layer CL of a polymer electrolyte fuel cell using a direct numerical simulation DNS model is presented. Two realizations of the bilayer catalyst layer structure are generated using a stochastic reconstruction technique with varied electrolyte and void phase volume fractions. The DNS calculations predict ...
متن کاملPolyaniline-derived Non-Precious Catalyst for the Polymer Electrolyte Fuel Cell Cathode
This paper focuses on a new polyaniline-derived non-precious cathode catalyst with high oxygen-reduction activity, verified in electrochemical and fuel cell testing. The rotating disk (RDE) onset and half-wave potential (E1⁄2) of oxygen reduction were measured at 0.90 V and 0.77 V, respectively. Rotating ring-disk electrode (RRDE) study revealed very good selectivity in the fourelectron reducti...
متن کاملEffect of CO in the reformatted fuel on the performance of Polymer Electrolyte Membrane (PEM) fuel cell
There are several obstacles to the commercialization of PEM fuel cells. One of the reasons is that the presence of carbon monoxide (CO) in the reformatted fuel, even at a very small scale, decreases the fuel cell performance. The aim of this paper is to investigate the effect of CO in reformatted fuel on PEM fuel cell performance. For this purpose, a steady state, one-dimensional and non-isoth...
متن کاملEvaluating Cathode Catalysts in the Polymer Electrolyte Fuel Cell
The polymer electrolyte membrane fuel cell (PEMFC) converts the chemical energy of hydrogen and oxygen (air) into usable electrical energy. At the cathode (the positive electrode), a considerable amount of platinum is generally required to catalyse the sluggish oxygen reduction reaction (ORR). This has implications regarding the cost in high-power applications, and for making a broad commercial...
متن کاملDesign of ordered-catalyst layers for polymer electrolyte membrane fuel cell cathodes
In polymer electrolyte membrane fuel cells (PEMFCs), because the reaction rate in the cathode is slower than that in the anode, the cathode catalyst layers require more catalyst loading than the anodes [1]. Much research has been focused on improving the catalytic activity in cathodes and simultaneously reducing the amount of Pt supported by carbon black, which is the most commonly used cathode...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Energies
سال: 2022
ISSN: ['1996-1073']
DOI: https://doi.org/10.3390/en15031179